There is probably no sensible way to seal between a wall and a slab that sticks out, possibly wrapping the whole thing with some form of baseboard that extends beyond the edge. Normally, you make sure that the wall is at the edge of the slab, so that the facade extends beyond the edge of the foundation. This of course assumes you have a foundation that can withstand the pressure, i.e., either a strong concrete slab or one that is edge-reinforced.
If you really want to build on a protruding foundation, you might be able to cast a small plinth on the slab before placing the sill there? Possibly paint with suitable paint...? I'm just guessing, of course.