Don't think it's asbestos. Looks like some glue/cement-like material.
Asbestos consists of sharp fibrous threads, I can't see any tendencies of this on the edges of what you're showing.
Yes, it seems to be some glue. However, you can't visually determine whether it's asbestos or not. You need to look at it under a microscope. I was mostly wondering if anyone has experience with asbestos being used behind door frames?
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