Well, there are no wonders here, the best that is somewhat easy to get is polyurethane foam (PUR) insulation used mainly for refrigerator insulation. It often has a lambda value lower than 30. You can find it at refrigeration companies. Next best is extruded polystyrene (XPS), available in well-stocked building supply stores. Lambda down towards 30. Compared to mineral wool which has a lambda around 40.